Korean Institute of Surface Engineering

pISSN : 1225-8024 | eISSN : 3399-8403


공학

한국표면공학회지 (27권3호 166-175)

A Study on the Development of Anode Material for Molten Carbonate Fuel Cell -Ni-Co anode-

용융탄산염 연료전지의 양극 및 대체재료의 제작에 관한 연구-Ni-Co양극에 관하여-

황상문;김선진;강성군;
;;;

한양대학교 재료공학과;
한양대학교 재료공학과;

Abstract

The effect of Co addition on the electrochemical performance and structural stability of porous Ni anode for molten carbonate fuel cell(MCFC) was evaluated by the anodic polarization and the sintering test in the simulated MCFC anode condition ($650^{circ}C$, 80% $H_2$+20%$CO_2$). The anode current density ranged from 110mA/$cm^2$ to 144mA/$cm^2$ was obtained at +100mV overpotential by additions of Co up to 10 wt.%. The sintering resistance of Ni-Co anodes was higher than that of the pure Ni anode. The increase of sintering resistance seemed to be to the lower diffusion coefficient of Co than that of Ni.

Keywords