Korean Institute of Surface Engineering

pISSN : 1225-8024 | eISSN : 3399-8403


공학

한국표면공학회지 (25권2호 73-81)

Composite coating of Suspended Inert Particles in the Rotating Disk Electrode

회전원판 전극에서 비활성 현탁분체의 복합도금

박세용;김래현;김진성;최창균;
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서울산업대학 화공과;서울대학교 화공과;
서울산업대학 화공과;서울대학교 화공과;

Abstract

The composite coating of suspended inert particles $alpha$-Al2O3 and copper from acid sulphate bath was investigated at the Rotating Disk Electrode. Effects of rotation speeds of electrode, physical properties of electrolyte, the size and concentration of suspended particles on the codeposition ratio of Al2O3 and the enhancement of mass transfer of copper ions were examined. Particularly, new experimental method for the measurement of the codeposition ratio was suggested and also the characteristics of the composite coating layer were measured by Rutherford Backscattering Spectrometry. Mass transfer of suspended particles system were increased up to 40% more than those of without suspended particles system. Optimum conditions of current density, hydrodynamics of RDE, and particles concentration showing maximum codeposition ratio were appeared in our experimental ranges. It was shown that the suspended inert particles were codeposited mainly near the surface of the composite coating layer.

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